Publication History: This article was prepared especially foe "Crain's Petrophysical Handbook" by E. R. (Ross) Crain, P.Eng., 2018.This webpage version is the copyrighted intellectual property of the author.

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NON-METALLIC MINERAL basicS
This page covers petrophysical analysis of non-metallic sedimentary  mineral such as halite, gypsum, trona, and sulphur. These minerals may be exploited for their commercial value, or may be encountered while drilling for oil and gas. A characteristic of these minerals is their low density, very high resistivity, and very low gamma ray response. Some have near zero neutron porosity response, but others have water of hydration with a corresponding specific neutron response.

Potash minerals  (sylvite, carnalite, langbeinite, polyhalite, kainite) and Coal analysis are covered elsewhere in this Handbook.

Halite, gypsum, and trona occur as relatively pure bedded minerals, thick enough to be resolved by well logs. These can be identified by their specific mineral properties as listed in the tables below, using lithology triggers. Alternatively, the mineral properties can be used in 2- or 3-mineral models, simultaneous equations, or multi-mineral probabilistic models.


In sulphur bearing rocks, lithology triggers will not work and the more sophisticated methods must be used. Crossplots, shown below the table of mineral properties, may also be helpful in confirming or eliminating possibilities.

 

 

NON-METALLIC  MINERAL PROPERTIES -- FRESH MUD

Mineral

PHIN

DENS

DTC

DTC

PE

Uma

Mlith

Nlith

Alith

Klith

Plith

 

Ls

g/cc

us/m

us/ft

barns

cu

frac

frac

frac

frac

frac

Water

1.000

1.00

656

200

0.10

0.10

Anhydrite

0.002

2.95

164

50.0

5.08

14.99

0.769

0.512

1.954

1.503

2.605

Halite

-0.010

2.03

220

67.1

4.72

9.58

1.291

0.981

1.020

1.316

4.583

Gypsum

0.490

2.35

172

52.4

4.04

9.49

1.093

0.378

2.647

2.894

2.993

Trona

0.350

2.08

213.3

65.0

0.71

1.48

1.250

0.602

1.662

2.077

0.657

Sulphur

0.020

2.02

400.3

122.0

5.05

10.20

0.765

0.961

1.041

0.796

4.951

 

NON-METALLIC MINERAL PROPERTIES -- SALTY MUD

Mineral

PHIN DENS DTC DTC PE Uma Mlith Nlith Alith Klith Plith
  Ls g/cc us/m us/ft barns cu frac frac frac frac frac
Water 1.076 1.10 620 189 0.10 0.11
Anhydrite 0.002 2.95 164 50.0 5.08 14.99 0.751 0.539 1.854 1.393 2.746
Halite -0.010 2.03 220 67.1 4.72 9.58 1.311 1.086 0.921 1.207 5.075
Gypsum 0.490 2.35 172 52.4 4.04 9.49 1.093 0.408 2.451 2.678 3.232
Trona 0.350 2.08 213.3 65.0 0.71 1.48 1.265 0.663 1.508 1.908 0.724
Sulphur 0.020 2.02 400.3 122.0 5.05 10.20 0.728 1.065 0.939 0.684 5.489



Standard crossplots with extended scales to show positions of halite and sulfur relative to the common sedimentary minerals.


HALITE  with / without ANHYDRITE
Halite or Rock Salt (NaCl) occurs in vast beds of sedimentary evaporite minerals that result from the drying up of enclosed lakes and oceans. Salt beds may be hundreds of meters thick and underlie broad areas. In the United States and Canada, extensive underground beds extend from the Appalachian basin of western New York through parts of Ontario and under much of the Michigan Basin. Other deposits are in Ohio, Kansas, New Mexico, Nova Scotia, Alberta, and Saskatchewan. Much of Europe into North Africa and western Asia are underlain by salt beds. In most cases, other evaporites, such as anhydrite (CaSO4)  and potash minerals, may be mixed or interbedded with the salt.

Salt domes are masses of salt that have been squeezed up from underlying salt beds by the weight of overlying rock, coming closer to or breaching the surface. Some domes are gypsum, not halite, but are still called "salt domes" because gypsum is technically a salt, although it is not very soluble and tastes terrible. Salt domes may contain anhydrite, gypsum, and native sulfur, in addition to halite. They are common along the Gulf coasts of Texas and Louisiana and are often associated with petroleum deposits. Germany, Spain, the Netherlands, Romania and Iran also have salt domes. Salt glaciers exist in arid Iran where the salt has broken through the surface at high elevation and flows downhill.

When exposed to water, anhydrite readily transforms to gypsum, (CaSO4·2H2O) by the absorption of water. This transformation is reversible, with gypsum forming anhydrite by heating to around 200 °C (400 °F) under normal atmospheric conditions.

Halite is used to preserve and flavour food and is essential for life. Industrial products are caustic soda and chlorine. Salt is used in many industrial processes including the manufacture of polyvinyl chloride, plastics, paper pulp, and many other products. Of the annual global production of around 200 million tonnes, about 6% is used for human consumption.

Salt can be derived from subsurface mining, solution mining, and evaporation of seawater. Some mines produce a million tons a year or more. Abandoned solution mines can be used for storage of natural gas as they are virtually leak proof. Specialized radial acoustic surveys are used to map the 3-D geometry of the cavern to assess its volume and potential risks.

HALITE-ANHYDRITE EXAMPLE
Visual Analysis rules:
  Halite:        gamma ray = near zero, resistivity = very high, density = 2030 (2.03 g/cc), PE = 4.7, DTC = 200 (67 us/ft)), neutron = near 0.0
  Anhydrite: gamma ray = near zero, resistivity = very high, density = 2970 (2.97 g/cc), PE = 5.0, DTC = 164 (50 us/ft)), neutron = near 0.0
These pure mineral values will vary by a small amount due to occluded water and other mineral inclusions.

The following example illustrates the two common methods for analyzing salt beds:


This example shows a very short portion of a log analysis of a salt with interbedded anhydrite. The top 20 meters uses a calcite-dolomite-anhydrite model with a PE-density-neutron 3-mineral model. A halite-anhydrite 2-mineral model could have been used in the salt in the lower portion of the image. However, results were determined using lithology triggers instead, giving sharper definition to the bed boundaries. Porosity in the salt is assumed to be zero so no hydrocarbons are present. Note the low gamma ray, high resistivity, and near zero neutron porosity. Density is near 3.0 g/cc in anhydrite and near 2.0 g/cc in salt.

GYPSUM
Gypsum (CaSO4·2H2O) is deposited from lake and sea water, as well as in hot springs, from volcanic vapors, and sulfate solutions in veins. It is often interbedded with the minerals halite, anhydrite, and sulfur-bearing limestone. When exposed to water, anhydrite readily transforms to gypsum by the absorption of water. When gypsum is heated in air it loses water and converts first to calcium sulfate hemihydrate, (bassanite), often simply called "plaster" and, if heated further, to anhydrous calcium sulfate (anhydrite).

It is used as a fertilizer, and as the main constituent in many forms of plaster, blackboard chalk, and wallboard. It is the hydrated form of anhydrite. A fine grained version of gypsum is known as alabaster, used in sculpture.

Gypsum is moderately water-soluble (2.0–2.5 g/l at 25 °C compared to 360 g/l for halite) and, in contrast to most other salts, it exhibits retrograde solubility, becoming less soluble at higher temperatures.

A good example of an exposed gypsum deposit is White Sands, New Mexico. A breached gypsum dome on Melville Island (Barrow Dome) in the Canadian High Arctic was the subject of a native sulphur exploration program in 1969. The sulphur was limited to erosion remnants on the surface. The author was project manager and a minor oil discovery was made at shallow depths on the south side of the dome.

Gypsum is produced from open pit mines throughout Europe, South Asia, Indonesia, Brazil, Canada, and USA. Some is produced as a by-product of smoke stack scrubbers at coal fired power plants.

GYPSUM EXAMPLE
Visual Analysis rules:
  Halite:        gamma ray = near zero, resistivity = very high, density = 2030 (2.03 g/cc), PE = 4.7, DTC = 200 (67 us/ft), neutron = near 0.0
  Anhydrite: gamma ray = near zero, resistivity = very high, density = 2970 (2.97 g/cc), PE = 5.0, DTC = 164 (50 us/ft)), neutron = near 0.0
  Gypsum:     gamma ray = near zero, resistivity = very high, density = 2235 (2.35 g/cc), PE = 4.0, DTC = 173 (52 us/ft), neutron = 0.49
These pure mineral values will vary by a small amount due to occluded water and other mineral inclusions.

Log analysis parameters are somewhat similar to coal but PE of coal is less than 1.0 and gypsum is near 4.0.

 

Gypsum example from western Kansas (image courtesy KGS)
Porosity scale is -10 to 30 percent with backup from 40 to 70 percent. Gypsum is recognized by its low gamma -ray value, very high neutron porosity exceeding 60% (due to the hydrogen contained in its water of crystallization) and density of 2.35 g/cc. The gypsum beds of the Blaine Formation are obvious on the example log section, and can be distinguished immediately from anhydrite, which has a neutron porosity of near zero and a heavy density of 2.98. An anhydrite bed is located at a depth of 1055 feet.

 


TRONA
Trona (Na2CO3•NaHCO3•2H2O) is an evaporite mineral formed in seasonal lakes, now buried under more recent sediments, some as deep as 1500 meters. Trona is found at Owens Lake and Searles Lake in California, the Green River Formation of Wyoming and Utah,  the Makgadikgadi Pans in Botswana, and in the Nile Valley in Egypt. Kenya, Turkey, and China are also home to significant trona resources. Most trona is recovered by subsurface mining, but small amounts are produced from brine wells, and by solution mining.

A related
carbonate mineral, nahcolite, has the composition of sodium bicarbonate (NaHCO3. It is mined in conjunction with or separately from Trona in some areas.

Trona is the primary source of sodium carbonate (Na2CO3) in the United States and to a lesser extent elsewhere. Sodium carbonate is also known as "soda ash" and is  rare in nature. It has many domestic and industrial uses, such as manufacturing glass, chemicals, paper, detergents, and textiles. It is also used to condition water, remove sulfur from both flue gases and lignite coals, and as a food additive.

When trona is heated to 500'C, both water and CO2 are driven off. This is followed by recrystalization from aqueous solution leaving sodium carbonate suitable for delivery to industrial customers. The USA has a vast reserve of trona, so it uses the heating of trona to produce about 25% of the world's supply. The alternate method of production is known as the Solvay process. It produces sodium carbonate in large quantities from halite (sodium chloride) and limestone (calcium carbonate). China produces nearly 50% of the world's supply, using both methods.

Many trona deposits are composed of multiple thin beds interspersed with marl or clay. Logs may have difficulty resolving beds less than 1 to 2 meters thick.

TRONA EXAMPLE
Visual Analysis rules:
  Marl/Clay: gamma ray = 50 -100,      resistivity = low,  density = 2300+/- (2.30 g/cc), PE = 3.5, DTC = 328 (100 us/ft), neutron = 0.30 - 0.40
  Trona:       gamma ray = near zero, resistivity = high, density = 2080     (2.08 g/cc), PE = 0.7, DTC = 213 (65 us/ft), neutron = 0.35
These pure mineral values will vary by a small amount due to occluded water and other mineral inclusions.

 


An ancient log from the Green River formation. Wyoming. contains beds of trona. The properties of this mineral are sufficiently different from the surrounding marl formation that logs clearly locate the trona beds.  The beds of trona are indicated by black shading. Marl is indicated by high GR and high sonic travel time, trona by low GR and lower sonic. Neutron for both is near 0.35 to 0.40, helping to eliminate other possible minerals in the clean intervals. Modern density neutron and high resolution resistivity logs would materially improve the visual interpretation.

 


Sulphur
The element Sulphur or Sulfur is a non-metallic element and, like halite, it is essential for life. In its native form, sulfur is a yellow crystalline solid. In sedimentary rocks, it is synthesized by anaerobic bacteria acting on sulfate minerals such as gypsum in salt domes. Significant deposits in salt domes occur along the Gulf of Mexico, and in evaporates in eastern Europe and western Asia. Salt domes are associated with traps for oil accumulation, so in drilling for oil considerable sulfur was discovered in the same wells.

In salt domes, the sulfur is usually a physical mixture with limestone, forming up to 50+% of the bulk volume of the rock. Some water filled porosity may be present. More complex mineral mixtures may also complicate the scene.

Elemental sulfur can also be found near hot springs and volcanic regions in many parts of the world, especially along the Pacific Ring of Fire; such volcanic deposits are currently mined in Indonesia, Chile, and Japan.

Salt-dome sulfur was mined by the Frasch process, in which superheated water was pumped into a native sulfur deposit to melt the sulfur, and then compressed air returned the 99.5% pure melted product to the surface. The melting point of sulfur is 115'C so considerable energy was expended in heating the sulfur zone. Throughout the 20th century this procedure produced elemental sulfur that required no further purification. Due to a limited number of such sulfur deposits and the high cost of working them, this process for mining sulfur has not been employed in a major way anywhere in the world since 2002.

Today, sulfur is produced mostly from petroleum, natural gas, and related fossil resources, from which it is obtained mainly as hydrogen sulfide (H2S). Known as an organosulfur compound, it can be upgraded to produce near-pure sulfur, resulting in the large yellow blocks of sulfur seen beside gas processing plants. The sulfur is shipped from here by truck or train to the many industrial firms that use it.

Elemental sulfur is used mainly as a precursor to other chemicals. Approximately 85% is converted to sulfuric acid (H2SO4). The principal use for the acid is the extraction of phosphate ores for the production of fertilizer manufacturing. Other applications include oil refining, wastewater processing, and mineral extraction. Sulfur itself is used in the manufacture of cellophane, rayon, medicines, and insecticides, Sulfates are used as a bleach for paper, as a component of Portland cement,  and as fertilizer.

Petrophysical analysis of logs for sulfur exploitation is no longer common, but we still need to be able to recognize it. Sulfur looks a lot like  porosity on sonic and density logs, and with the high resistivity, it can be mistaken for a hydrocarbon zone based on standard visual analysis rules. There are some rules below that might help avoid this problem.

Quantitative methods reduce the risk of misinterpretation. Three-mineral simultaneous equation model with calcite, sulfur, and water will work, using sonic, density, and neutron data. If another mineral is present, such as anhydeite or gypsum, lithology triggers or a fourth equation using the PE curve can be added.

By using the characteristic mineral and water properties in the response equations for the limestone-sulfur case, we get:
      1: Vsulfur = (PHID - PHIN) / 0.40
      2: Vsulfur = (PHIS - PHIN) / 0.53

Where:
  PHID = density porosity on a limestone scale (fractional
  PHIN = neutron porosity on a limestone scale (fractional
  PHIS = sonic porosity on a limestone scale (fractional

SULPHUR EXAMPLE
The above equations lead to some simple visual rules for a calcite-sulfur mixture:
  1. PHIN = actual water filled porosity
  2. PHID = PHIN = Limestone, with no sulfur, water or oil depending on resistivity
  3. PHID > PHIN = limestone, with sulfur
  4. PHID << PHIN = Anhydrite, no porosity, no sulfur
 

Ancient density neutron overlay in sulfur bearing rock. Diagonal  crosshatch = sulfur zone, bricks = limestone, xxxx  = anhydrite.
 

REFERENCES:
   1. Defining Evaporite Deposits with Electrical Well Logs
   R. P. Alger, E. R. Crain
, P.Eng.
   Trans Northern Ohio Geological Society - Second Symposium on Salt, Cleveland, 1966
  


  2. Log Evaluation of Non-Metallic Minerals
  M.P. Tixier, R. P. Alger,SWSC, 1967, Geophysics Vol 35 #1, 1970
  
 

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